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Substituent Effects on the Ionization Step Regulating Desorption and Catalytic Oxidation of Alcohols Bound to Liver Alcohol Dehydrogenase

✍ Scribed by Jan KVASSMAN; Anita LARSSON; Gösta PETTERSSON

Book ID
115119797
Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
993 KB
Volume
114
Category
Article
ISSN
1432-1327

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On a possible invariance of a transition
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✍ R. Cárdenas; J. Andrés; J. Krechl; M. Campillo; O. Tapia 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 1020 KB

The influence of a hydroxyl group simulating Ser-48 in the hydride-transfer step characteristic of liver alcohol dehydrogenase is studied on the hydride-transfer reaction as modeled by a methanolate anion interacting with a cyclo propenyl cation. It is shown first that this is an adequate model by c