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Substituent Effects on Regioselectivity in the Autoxidation of Nonconjugated Dienes

✍ Scribed by Tallman, Keri A.; Rector, Christopher L.; Porter, Ned A.

Book ID
111943110
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
634 KB
Volume
131
Category
Article
ISSN
0002-7863

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Substituent Effects on Regioselectivity
Substituent Effects on Regioselectivity in the Photorearrangement of a Few Naphthobarrelenes
✍ Meledathu C Sajimon; Danaboyina Ramaiah; S Ajaya Kumar; Nigam P Rath; Manapurath πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 151 KB

AbstractÐThe photorearrangement of a few 9,10-disubstituted-naphthobarrelenes to the corresponding naphthosemibullvalenes has been examined. It was observed that the regioselectivity in these photoisomerizations depends on the relative stabilities of the diradical intermediates. AM1 semi-empirical c