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Substituent Effects on P−C Reductive Elimination from Styrylpalladium(II) Phosphine Complexes †

✍ Scribed by Wakioka, Masayuki; Ozawa, Fumiyuki


Book ID
127049605
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
1002 KB
Volume
29
Category
Article
ISSN
0276-7333

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Steric and electronic effects on 195Pt N
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## Abstract Platinum‐195 chemical shift measurements for __cis__‐PtCl~2~(PCy~3~)~2~ and __trans__‐PtXCl(PCy~3~)~2~ (X = H, Cl, SnCl~2~Ph and SnCl~3~) in methylene chloride solution are reported. A comparison of these shifts with those from analogous complexes containing less bulky phosphine ligands