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Substituent effects on intramolecular dipolar cycloadditions: The gem-dicarboalkoxy effect

โœ Scribed by Michael E Jung; Binh T Vu


Book ID
103403200
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
193 KB
Volume
37
Category
Article
ISSN
0040-4039

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Comparison of the rates of cyclization of a series of 2-furfuryl methyl fumarates leads to the conclusion that the gem-dimethyl effect is due primarily to higher population of reactive rotamers. Our recent observation of significant rate acceleration of the infmmolecular Diels-Alder reaction of N-f