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Substituent effects on 13C and 1H chemical shifts in 2-isopropyl- and 2,6-diisopropylnaphthalene and their oxidation products

✍ Scribed by Roman Mazurkiewicz; Zbigniew Stec; Jan Zawadiak

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
95 KB
Volume
38
Category
Article
ISSN
0749-1581

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✦ Synopsis

13

C and 1 H spectral assignments were made for three 2-substituted-and six 2,6-disubstituted naphthalenes with isopropyl, 2-hydroxy-2-methylethyl and 2-hydroperoxy-2-methylethyl substituents by the use of proton-proton decoupling, 2D H,H-COSY and 2D-C,H-COSY techniques. The downhill simplex method was used for calculations of the best set of 13 C and 1 H incremental shifts. An excellent additivity of substituent effects was found for both, the 13 C and 1 H spectra of 2,6-disubstituted naphthalenes.

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