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Substituent effects in heterogeneous catalysis: VIII. Reactions of 2-methyl- and 2-ethylcyclohexanone with deuterium catalyzed by platinum metals

โœ Scribed by Shousuke Teratani; Kazunori Tanaka; Haruo Ogawa; Kazuo Taya


Book ID
113176762
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
619 KB
Volume
70
Category
Article
ISSN
0021-9517

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A very high S-deuterium kinetic isotope effect, k(CH3)/k(CD3) =2.l3 at ~o'c, was found for the solvolysis of 2-(3'-chlorophenyl)-l,l,l-trifluoro-2propyl tosylate(&) and the a-CD3 analogue