Substituent Effects in Carbocations Substituted at a Charged Carbon Atom
β Scribed by Marvin Charton; Barbara I. Charton
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 59 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0037-9646
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π SIMILAR VOLUMES
It is shown that the y, effects of hetero substituents on the "C chemical shift (7, SCS) are enlarged by +2 to +5 ppm by substituting the a-hydrogen atom by any group or atom (e.g. CH,, OR, F, (3, Br). The same is encountered when the axial y-hydrogen is replaced by CH3, OH or F. If, however, the su
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