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Substituent Effect on the Formation and Reactivity of Platinum Carbenoids

✍ Scribed by Eun Jin Cho; Daesung Lee

Publisher: John Wiley and Sons
Year: 2008
Tongue: English
Weight: 161 KB
Volume: 350
Category: Article
ISSN: 1615-4150
DOI: 10.1002/adsc.200800544

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✦ Synopsis

Abstract

A propargylic ester containing a propargylic alkoxy group has been observed to preferentially undergo [1,2]‐acyl shift over [1,3]‐shift. In addition, the complementary and contrasting reactivity of vinyl vs. alkynyl platinum carbenoids has been discovered. Vinyl platinum carbenoids are more prone to undergo [1,2]‐H shift over addition to π‐bonds whereas alkynyl platinum carbenoids preferentially add to π‐bonds.

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