The central phenylene ring o f I ,4-bis(3,4-dimethylphosphol-1-yobenzene undergoes [ I ,5] shifts around both phospholyl rings above 150Β°C to give 1,4-bis(3,4-dimethyl-SH-phosphol-2-yl)benzene, which can be trapped by tolane, [CpFe(CO)zlz, or Mn2 (CO)lo to yield the corresponding bis-1 -phosphanorbo
β¦ LIBER β¦
Substituent Effect on a [1,5] Sigmatropic Ester Shift
β Scribed by Dipl.-Chem. Jutta Backes; Prof. Dr. Reinhard W. Hoffmann; Prof. Friedrich W. Steuber
- Publisher
- John Wiley and Sons
- Year
- 1975
- Tongue
- English
- Weight
- 111 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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