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Substituent Effect on a [1,5] Sigmatropic Ester Shift

✍ Scribed by Dipl.-Chem. Jutta Backes; Prof. Dr. Reinhard W. Hoffmann; Prof. Friedrich W. Steuber


Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
111 KB
Volume
14
Category
Article
ISSN
0044-8249

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Non-hear Anhenius plots and large kmetk tsotope effects observed III slgmatropic hydrogen shifts of photochemlclllly generated tramlent di-and he?ra-hydrocarbuoles are interpreted as tunnel contrlbutlons An Eckti bamer was used to cddate the quantum-mechanrcal transmtssion probabiiticsof the tunnebn