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Substituent effect in benzylic oxidation by palladium(II) acetate

✍ Scribed by C.Hackett Bushweller


Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
164 KB
Volume
9
Category
Article
ISSN
0040-4039

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Benzylic oxidation with palladium(II) ac
✍ David R. Bryant; James E. McKeon; Bernard C. Ream πŸ“‚ Article πŸ“… 1968 πŸ› Elsevier Science 🌐 French βš– 149 KB

Sometime ago, we discovered that palladium(I1) acetate is an efficic'::t reagent for benzylic oxidation of alkylbenzenes. For example, healing a mi\_\ture of 0.10 mole of toluene, 0.20 mole of potassium acetate, and 0.01 mole of palladium(I1) acetate in 1.67 moles of acetic acid at 100' for 5 hours