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Substituent control of the regiospecificity of trifluoroacetic acid addition to an allene

โœ Scribed by Macomber, Roger S.


Book ID
126231203
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
255 KB
Volume
42
Category
Article
ISSN
0022-3263

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Novel regiospecificity in the acid-catal
โœ M.A. Battiste; J.M. Coxon; R. Edelman ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 170 KB

We report a striking example of unprecedented regiospecificity in the addition of acetic acid to endo-tricyclo[3.2.1.0z"]oct-6-ene (1). The addition proceeds with surprising ease in acetic acid at 80' (3 days) or at room temperature in the presence of catalytic amounts of toluenesulphonic acid to yi