Subpicosecond solvation relaxation of DASPI in polar liquids
β Scribed by A.M. Jonkman; P. van der Meulen; H. Zhang; M. Glasbeek
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 448 KB
- Volume
- 256
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
A hydrodynamic model of electron solvation in polar liquids is suggested. The electron is assumed to be localized within a spherical cavity in an ideal incompressible liquid. The solvation process is modelled by the contraction of the cavity size to its equilibrium value. The contraction dynamics ar
Spin-lattice relaxation times of acetonitrile, aligned by an electric field, have been measured. In contrast to earlier investigations on other polar liquids, no electric-field effects on T1 could be established. The apparent discrepancy is discussed in terms of electric conduction and inhomogeneity