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Submillimeter-Wave Absorption Spectroscopy of the Ar–CO Complex: Detection of the van der Waals Bending Vibration

✍ Scribed by M. Hepp; R. Gendriesch; I. Pak; F. Lewen; G. Winnewisser

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
109 KB
Volume
183
Category
Article
ISSN
0022-2852

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✦ Synopsis

Van der Waals bending rovibrational transitions of the Ar-CO complex were observed between 308 and 383 GHz using submillimeter-wave absorption spectroscopy in a pulsed supersonic jet. The submillimeter radiation was generated by a phase-stabilized backward wave oscillator source. Fourteen transitions of the P and R branch of the bending vibration were measured with an accuracy of about 100 kHz. The frequencies were fitted using effective molecular parameters including the band origin and the rotational constants for the ground state and for the excited bending vibrational state.

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