Submicro methods for the analysis of organic compounds : The determination of hydroxyl groups

✍ Scribed by R. Belcher; G. Dryhurst; A.M.G. Macdonald

• Publisher: Elsevier Science
• Year: 1967
• Tongue: English
• Weight: 834 KB
• Volume: 38
• Category: Article
• ISSN: 0003-2670
• DOI: 10.1016/s0003-2670(01)80607-3

✦ Synopsis

'erj* n1iin>. rilctl~cds Ili~vct Ixwl clcwrilwtl ft)r tlic cl~tCrlllillilti~jll of Iiydrosyl groule in organic c~o~ll~~oullCl~* -.$. 'I'lic lcnctivit\* of tllis grou1J iS Iligllly dcpcnclcnt on its pilrti(:Ul:lr collll>iniltioll in ;I IIlolcCUlC, SO tllilt 110 single Ill~!tllOO Cilll IlC ill>1>liccI to ilII ~IilSis~S Of CCJI~~~JOUI~CI. I:stcrific3tic~ii IllctlloCls ilW tlw IlloSt \vitlcly il1>1>lil*ill)lC and \vcrc tlwrcforc ~.~illlliIlC<l fc,,r ~ltlil~JtiltiOll to tilt! sulmiiux~ SC'illC. Howcvcr, tllc tlifficulties foullcl lllaclc it llcc:cSsary to tiit\wlo1l illtC!rIlilti'C lwoccxlurcs illlcl su!!Illic*rcJ ilClil1~tilti~~ll.S Of I~roIllillittion IIlilCC C'VCfl * r\ftcr the conlplction of this \vork. Dr. Cl~ITcIIFII!LI~ (priviltc corllnllcllicntiot1) ztntctl that none of the tlifficulticv incntionccl on p. 4.10 Wc'rc found when the p)'riclinc \va?i tlrictl with rnolccuhr sicxw which rcm~ovcs not only water but also srnnll polar org;rnic molcculce.