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Sub-picosecond relaxation of large organic molecules in solution

✍ Scribed by C.V. Shank; E.P. Ippen; Omar Teschke


Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
330 KB
Volume
45
Category
Article
ISSN
0009-2614

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✦ Synopsis


Using sub-picosecond ultraviolet and visrble pulses we have studied relaxations from highly-excited molccular vΓ―bronic states witb a resolution of 2 X lOsz s.

Picosecond pulses have been utilized by a number

of workers to investigate radiationless relaxation of large organΓ―c molecules in solution Cl-63 _ In this


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Theoretical analysis of the time-dependent triplet-triplet absorption spectrum of anrhracene is cvried out in terms of the Huanp-Rhys spectral function which describes the absorption of molecules thermally equilibrated, due to fast intramolecular processes, al some effective tempera!urc r\*(r) depen