Polypropylene/polyamide 6 blends were prepared by melt mixing, without or with the addition of a suitable commercial product, a polypropylene grafted with 1% maleic anhydride, used as an interfacial modifier. The oxygen permeation through their films was studied as a function of temperature and the
Study on the microstructures and mechanical behaviour of compatibilized polypropylene/polyamide-6 blends
✍ Scribed by N Zeng; S L Bai; C G'Sell; J-M Hiver; Y W Mai
- Book ID
- 104526630
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 438 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0959-8103
- DOI
- 10.1002/pi.1080
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
A series of blends of polypropylene (PP)–polyamide‐6 (PA6) with either reactive polyethylene–octene elastomer (POE) grafted with maleic anhydride (POE‐g‐MA) or with maleated PP (PP‐g‐MA) as compatibilizers were prepared. The microstructures and mechanical properties of the blends were investigated by means of tensile and impact testing and by scanning electron microscopy and transmission electron microscopy. The results indicated that the miscibility of PP–PA6 blends was improved with the addition of POE‐g‐MA and PP‐g‐MA. For the PP/PA6/POE‐g‐MA system, an elastic interfacial POE layer was formed around PA6 particles and the dispersed POE phases were also observed in the PP matrix. Its Izod impact strength was four times that of pure PP matrix, whilst the tensile strength and Young's modulus were almost unchanged. The greatest tensile strength was obtained for PP/PA6/PP‐g‐MA blend, but its Izod impact strength was reduced in comparison with the pure PP matrix.
© 2002 Society of Chemical Industry
📜 SIMILAR VOLUMES
Using reactive extrusion, polypropylene is functionalized with maleic anhydride and compared on an equimolar basis to polypropylene that is functionalized with an asymmetric, carboxylic acid containing peroxide. The grafting efficiency for the asymmetric peroxide is double that obtained for the male