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Study on the lithium solid electrolytes of Li3NLi3BiLiCl ternary system — 2Li3Bi · 3LiCl lithium solid electrolyte

✍ Scribed by Jinxian Yang; Yongzhong Jia; Zhixiang Yao

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
254 KB
Volume
96
Category
Article
ISSN
0167-2738

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✦ Synopsis

Lithium solid electrolyte 2Li,Bi .3LiCI was prepared and was characterized by X-ray diffraction and X-ray photoelectron spectroscopy (XPS). The electrical conductivity of the prepared sample was determined from room temperature to 250°C by PAR 368-l AC-impedance spectrometer.

The frequency measurement range was between 4 Hz and 100 kHz. The experimental results showed that the 2Li,Bi .3LiCl lithium solid electrolyte has a high conductivity of about I X 10m4 S/cm at 100°C and 1 X IO-' S/cm at 350°C.

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Study of the lithium solid electrolytes based on lithium nitride chloride (Li9N2Cl3)
✍ Yongzhong Jia; Jinxian Yang 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 361 KB

Lithium nitride chloride (Li,N,Cl,) is a fast solid lithium ion conductor. According to analytical data from X-ray diffraction, DSC, DTA and conductivities, we found that a phase transition could take place when Li,N,Cl, is at 250°C. Lithium solid electrolytes of Li,\_,M,N,Cl, (M = Na', K', Rb+, Cs'