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Study on reactivity of pentacoordinate bicycloazastannoxides. I. Aldol condensation with aldehydes

✍ Scribed by Jitao Wang; Xiaoping Yang

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 360 KB
Volume: 7
Category: Article
ISSN: 1042-7163
DOI: 10.1002/(sici)1098-1071(199605)7:3<211::aid-hc9>3.0.co;2-c

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✦ Synopsis

The condensation of a-carbanions formed from pentacoordinate bicycloazastannoxides with aldehydes was investigated. Nine novel organotin(IV) complexes with P-hydroxy-a-amino acids were synthesized. Their structures were determined by IR, ' H NMR, If9Sn NMR spectroscopy, MS, and elemental analyses. The reaction mechanism is discussed.

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