## Abstract This paper reports a simple and highly selective method for preconcentrating and separating of trace Pd(II) and Pt(IV) with silica gel bonded by aminopropyl‐benzoylazo‐4‐(2‐pyridylazo)‐resorcinol (ABPR·SG). ABPR·SG is stable in solution from 6 mol/L HCl to pH 7.0 and in common organic s
Study on Preconcentration and Separation of Trace Pd(II) and Pt(IV) with Silica Gel Bonded by Aminopropyl-benzoylazo-1-(2-Pyridylazo)-2-Naphthol
✍ Scribed by F. Liu; K.A. Li; Y.S. Wu; X. Wang; S.Y. Tong
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 285 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0026-265X
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✦ Synopsis
This paper reports on preconcentration and separation of trace (\mathrm{Pd}(\mathrm{II})) and (\mathrm{Pt}(\mathrm{IV})) with silica gel bonded by aminopropyl-benzoylazo-1-(2-pyridylazo)-2-naphthol (ABPN - SG). ABPN - SG is stable in solution between (6 \mathrm{~mol} /) liter (\mathrm{HCl}) and (\mathrm{pH}) 9.0. The maximum adsorptive capacity of (\mathrm{Pd}() II) on (\mathrm{ABPN}). SG is (96 \mu \mathrm{mol} / \mathrm{g}). After preconcentration and separation using an ABPN . SG column, Pd(II) and (\mathrm{Pt}(\mathrm{IV})) of (\mathrm{pph}) level in artificial water samples can be measured by spectrophotometry. (c) 1995 Academic Press, Ins.
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