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Study on Improving the Turbidity Measurement of the Absolute Coagulation Rate Constant

✍ Scribed by Sun, Zhiwei; Liu, Jie; Xu, Shenghua


Book ID
121385532
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
97 KB
Volume
22
Category
Article
ISSN
0743-7463

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πŸ“œ SIMILAR VOLUMES


An absolute measurement of the rate cons
✍ D. M. Golden; K. Y. Choo; M. J. Perona;; L. W. Piszkiewicz πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 English βš– 290 KB πŸ‘ 1 views

An absolute value of k, of ethyl radicals at 860 f 17Β°K of 4.5 X l o 9 M-l.sec-' was determined under VLPP conditions, where the value of k,/k," should be about M. Thus k,"(M-'.sec-') -10' 0 at 860Β°K. An error of as much as a factor of 2 in k, would be surprising, but possible. The value of lO'OM-'

An absolute measurement of the rate cons
✍ K. Y. Choo; P. C. Beadle; L. W. Piszkiewicz; D. M. Golden πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 English βš– 584 KB

## Abstract The rate constant for __tert__‐butyl radical recombination has been measured near 700Β°K by the very‐low‐pressure pyrolysis (VLPP) technique and was found to be 10^8.8Β±0.3^ __M__^βˆ’1^Β·sec^βˆ’1^ with neglibible temperature dependence. The thermochemical parameters for __tert__ο£Ώbutyl radicals

An indirect measurement of the absolute
✍ S. King Wong πŸ“‚ Article πŸ“… 1981 πŸ› John Wiley and Sons 🌐 English βš– 594 KB

## Abstract No reliable rate constant is available for the self‐reaction of __tert__‐;butoxy radicals. We have set up a competition between hydrogen abstraction and self‐reaction of __tert__‐butoxy radicals in a flash photolysis electron spin resonance study to extract this information. Experimenta

Comments on the determination of absolut
✍ S. Bywater πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 127 KB πŸ‘ 1 views

Claims have recently been made that absolute rate constants for chain propagation of the unassociated active centers can be made in systems where a high degree of association is present. Anionic polymerization of styrene in nonpolar solvents with lithium as counterion is a typical case. The conditio