Study of vibrational dephasing and frequency shifts in hydrogen-bonded systems by four-channel raman difference spectroscopy

✍ Scribed by B.P. Asthana; H. Takahashi; W. Kiefer

• Publisher: Elsevier Science
• Year: 1983
• Tongue: English
• Weight: 573 KB
• Volume: 94
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(83)87207-8

✦ Synopsis

The isotropic Raman b.md\xidths and frequency shifts of the Y, (rinz) mode of hydrogen-bonded specks CsIlsN...IIOCH~ hme been meosured as a function of conccntratmn of CsHsN in P mz.xturc ofC5ilSN + Cl130H cmplo> ma the techmquc of four-chsnnel Raman difference spectroccop) _ The concentntion dependence of frequency shifts 2nd bsndxxidths 11.~ e been e.tmincd and the concentration-independent (intrinsic) bandwidth C\pkiinCd bl the cwhan&w model of Kubo .md Anderson.