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Study of uranyl(VI) ion reduction at various ionic strengths of sodium perchlorate

✍ Scribed by Renata Djogić; Marko Branica


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
608 KB
Volume
281
Category
Article
ISSN
0003-2670

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✦ Synopsis


To determine the number of water molecules involved in the electrode reaction of the uranyl(VI)-(V) redox pair, square-wave voltammetric measurements of uranyl(VI) ion reduction in non-complexing NaCIO, media at pH 2 and different ionic strengths between 0.1 and 8.5 mol I-' were performed. The available literature water activity data were compared and taken into account. The loss of two water molecules was established.


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## Abstract The variation of the activity coefficient of some cations and of the ratio of the activity coefficients of the ions of some redox systems with the hydrogen ion concentration has been measured at several (constant) values of ionic strength in perchloric acid‐sodium perchlorate and perchl