Study of uranyl(VI) ion reduction at various ionic strengths of sodium perchlorate
✍ Scribed by Renata Djogić; Marko Branica
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 608 KB
- Volume
- 281
- Category
- Article
- ISSN
- 0003-2670
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✦ Synopsis
To determine the number of water molecules involved in the electrode reaction of the uranyl(VI)-(V) redox pair, square-wave voltammetric measurements of uranyl(VI) ion reduction in non-complexing NaCIO, media at pH 2 and different ionic strengths between 0.1 and 8.5 mol I-' were performed. The available literature water activity data were compared and taken into account. The loss of two water molecules was established.
📜 SIMILAR VOLUMES
## Abstract The variation of the activity coefficient of some cations and of the ratio of the activity coefficients of the ions of some redox systems with the hydrogen ion concentration has been measured at several (constant) values of ionic strength in perchloric acid‐sodium perchlorate and perchl