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Study of the vibrational photochemical reaction of uranium hexafluoride + hydrochloric acid and its isotopic selectivity

โœ Scribed by Xu, Baoyu; Liu, Yong; Dong, Wenbo; Zhao, Wi; Hu, Jianxun; Zheng, Chengfa


Book ID
120037027
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
466 KB
Volume
96
Category
Article
ISSN
0022-3654

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The kinetics of the isotope exchange reactions of RCH(COOH) 2 (R"H, D, Me, Et, Bu, and Ph) in D 2 O solution were studied by using 1 H NMR spectroscopy. It was observed that the rate of isotope exchange reaction was inhibited by the presence of 1 M of DNO 3 , DCl, DBr or D 2 SO 4 and catalyzed by th