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Study of the synthesis and properties of [25](1,2,3,4,5)cyclophane

โœ Scribed by Schirch, Paulo F. T.; Boekelheide, V.


Book ID
126004535
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
834 KB
Volume
103
Category
Article
ISSN
0002-7863

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Multibridged [3n]Cyclophanes, 1. Synthes
โœ Shinmyozu, Teruo ;Kusumoto, Shirou ;Nomura, Sachiyo ;Kawase, Haruo ;Inazu, Takah ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 453 KB ๐Ÿ‘ 2 views

The acid-catalyzed cyclization of a pseudogeminally substituted acetyl group and a chloromethyl group of tri-bridged cyclophane 7 , followed by reduction of the carbonyl group afforded (3,](1,2,3,5)cyclophane 3. One-step TosMIC coupling reaction of tetrabromide 12 and subsequent reduction of the car