Study of the Structure and Photochemical Decomposition of Azidoadamantanes Entrapped in α- and β-Cyclodextrin
✍ Scribed by Udo H. Brinker; Peter Walla; Daniel Krois; Vladimir B. Arion
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 752 KB
- Volume
- 2011
- Category
- Article
- ISSN
- 1434-193X
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Molecular mechanics calculations were employed to study the inclusion of 2-methyl naphthoate in alpha- and beta-cyclodextrin in vacuo and in the presence of water as a solvent. The driving forces for complexation are dominated by nonbonded van der Waals host:guest interactions in both environments.
The complexation of ferrocene and several ferrocene derivatives with the hosts a-cyclodextrin (a-CD) and b-cyclodextrin (b-CD) was investigated by electrospray mass spectrometry. A 2:1 complex was detected between a-CD and ferrocene while a 1:1 complex was observed with b-CD and this organometallic