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Study of the solvent effect on the Raman spectrum of I2 and IBr. Comparison with Br2 ag

โœ Scribed by J. Put; G. Maes; P. Huyskens; Th. Zeegers-Huyskens

Book ID
103906960
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
664 KB
Volume
37
Category
Article
ISSN
1386-1425

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โœฆ Synopsis

The Raman parameters of iodine and iodine bromide dissolved in various organic solvents have been studied. The relative frequency shift, the band width, the depolarization ratio and absolute intensity are discussed in terms of dispersion forces, interaction between permanent dipoles and specific interactions between the solvents and the solute. Marked differences are observed between the polar (IBr) and apolar (I*) molecules.

๐Ÿ“œ SIMILAR VOLUMES

Kinetic study of the reactions Br + IBrโ†’
Kinetic study of the reactions Br + IBrโ†’I + Br2 and I + Br2โ†’Br + IBr
โœ Y. Bedjanian; G. le Bras; G. Poulet ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 174 KB ๐Ÿ‘ 2 views

The kinetics of the title reactions have been studied using the discharge-flow mass spectrometic method at 296 K and 1 torr of helium. The rate constant obtained for the forward reaction (1), using three different experimental approaches (kinetics of Br Br ฯฉ IBr : I ฯฉ Br 2 consumption in excess of