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Study of the pyrochlore-related structure of α-Cs2U4O12 by powder neutron and X-ray diffraction

✍ Scribed by S. Van den Berghe; J.P. Laval; M. Verwerft; B. Gaudreau; E. Suard


Book ID
114370479
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
579 KB
Volume
4
Category
Article
ISSN
1293-2558

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3-SrRh204 , a novel high temperature phase, is prepared as black powder by solid state reaction of SrCO3 with Rh in air. The compound crystallises in the space group P63c, Z = 1, with a = 3.0626(2) A and c = 11.3996(7) A. The structure consists of CdI2-type layers of edge sharing RhO6 octahedra with