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Study of the Pyrimidine Nucleobase C5—C6 Bond Reactivity under Thio-Michael/Aldol Tandem Reaction Conditions.

✍ Scribed by Edna Vazquez Velez; Celine Desnous; Pascale Clivio

Publisher: John Wiley and Sons
Year: 2007
Weight: 20 KB
Volume: 38
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200701203

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✦ Synopsis

Abstract

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Study of the pyrimidine nucleobase C5C6

Study of the pyrimidine nucleobase C5C6 bond reactivity under thio-michael/aldol tandem reaction conditions

✍ Edna Vázquez Velez; Céline Desnous; Pascale Clivio 📂 Article 📅 2006 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 86 KB

## Abstract magnified image Pyrimidine nucleobases can undergo a Michael/aldol tandem reaction triggered by a thiolate. In an intramolecular context, 5′‐deoxy‐2′,3′‐isopropylidene‐5′‐thiouridine affords the reminiscent Baylis‐Hillman adduct after retro‐Michael addition whereas its thymine counterp