Complexes o f Pd(1I) w i t h 2 amino-4,6 dimethylpyrimidine have been studied employing elemental analysis, thermal analysis, U.V.-Vis, i n f r a r e d and Raman techniques. The complexes have been i s o l a t e d a t PdL2C12(A). Pd2LjC14(B). PdC12.3H20(C) and Pd2L2Br3.3H20(0). The metal i s bound
Study of the PD(II) Complexes with 4 Hydroxy Pyrimidine Hydrochloride
β Scribed by D. Kovala-Demertzi; J. M. Tsangaris; H. D. Desseyn
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 83 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0037-9646
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β¦ Synopsis
Studies o f Pd(I1) complexes w l t h pyrlmldlne have been subject o f many investigations (1). I n t h i s cannunicatlon we present the synthesls. the e l e c t r o n l c spectra and the v l b r a t l o n a l spectra o f Pd(I1) complexes w l t h 2-hydroxypyrlmidine.
The I n t r w n t a t l o n and procedures have already been reported I n e a r l l e r papers (1)(2).
K2PdC14 and 2-hydroxypyrlmldlne hydrochlorlde (HPHCL) were purchased from Fluka Chemical Company. A l l the r e s u l t s and chemicals used were h l g h p u r l t y .
π SIMILAR VOLUMES
The synthesis and spectral characterization of a new triangular, trinuclear palladium(II) complex with the dianion of 2hydroxy-4-methoxyacetophenone N 4 -dimethylthiosemicarbazone, 4MeOAp4Me 2 2-is reported. The X-ray crystal structure determination of [Pd(4MeOAp4Me 2 )] 3 β DMSO shows it
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