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Study of the Partial Oxidation of Methanol to Formaldehyde on a Polycrystalline Ag Foil

✍ Scribed by Beuhler, R. J.; Rao, R. M.; Hrbek, J.; White, M. G.

Book ID
126124351
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
92 KB
Volume
105
Category
Article
ISSN
0022-3654

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Density functional theory study of the o
Density functional theory study of the oxidation of methanol to formaldehyde on a hydrated vanadia cluster
✍ P. GonzΓ‘lez-Navarrete; L. Gracia; M. Calatayud; J. AndrΓ©S πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 1013 KB

Density functional theory was used to study the mechanism for the oxidation of methanol to formaldehyde. A vanadium oxide cluster OΒΌ ΒΌV(OH) 3 has been utilized to represent the catalytic system under hydrated conditions, i.e., in the presence of VΓ€ Γ€OH hydroxyl groups. Two types of methoxy-intermedi