Study of the ion role in the magnetic properties of the AFM ring using Mössbauer spectroscopy
✍ Scribed by L. Cianchi; F. Del Giallo; M. Lantieri; P. Moretti; G. Spina; G. Timco; R. Winpenny
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 644 KB
- Volume
- 150
- Category
- Article
- ISSN
- 0038-1098
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✦ Synopsis
In recent years the synthesis of antiferromagnetic rings traced a path to the observation of interesting quantum coherence phenomena in heterometallic Single Molecule Magnets. Because of the presence of different magnetic centers, it is crucial to understand the distribution of the molecular spin on all the sites. 57 Fe Mössbauer spectroscopy is an efficient and powerful technique to contribute to this knowledge in antiferromagnetic wheels containing iron ions. We analyze the Cr 7 Fe II wheel: the Mössbauer line shape evolution of low temperature spectra (2.1 K) at different external fields is illustrated and the mean spin value of the iron ion is evaluated.
📜 SIMILAR VOLUMES
A brief introduction to the methodology of the M6ssbauer spectroscopy will be given. The main applications to the study of the intrinsic properties of the materials employed in the electronic technology are reviewed. The reported examples prove the effectiveness of this technique in the study of se