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Study of the ion role in the magnetic properties of the AFM ring using Mössbauer spectroscopy

✍ Scribed by L. Cianchi; F. Del Giallo; M. Lantieri; P. Moretti; G. Spina; G. Timco; R. Winpenny


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
644 KB
Volume
150
Category
Article
ISSN
0038-1098

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✦ Synopsis


In recent years the synthesis of antiferromagnetic rings traced a path to the observation of interesting quantum coherence phenomena in heterometallic Single Molecule Magnets. Because of the presence of different magnetic centers, it is crucial to understand the distribution of the molecular spin on all the sites. 57 Fe Mössbauer spectroscopy is an efficient and powerful technique to contribute to this knowledge in antiferromagnetic wheels containing iron ions. We analyze the Cr 7 Fe II wheel: the Mössbauer line shape evolution of low temperature spectra (2.1 K) at different external fields is illustrated and the mean spin value of the iron ion is evaluated.


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