The RandIes cwcult well represent, lmpednnce me;Lbur carried out \rlth actuated Pt electrode3 This enables us to .tud\ the \arl;ltlon at, for redo\ redctwn> \rlth concentratton ol the reactants at cowant potentldl. and Ao the \drlatton ot 1 \\lth potcntlal keeping constant the corwentrntwn ot one ol
Study of the impedance of a platinum electrode in the system Br2/Br− (HClO4, aq.). I. Influence of the surface state
✍ Scribed by J. Llopis; M. Vàzquez
- Publisher
- Elsevier Science
- Year
- 1962
- Tongue
- English
- Weight
- 595 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0013-4686
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A Randles circuit has been used as a first approximation to explain the a.c. impedance of a platinum electrode in the system Cl&l-(HCIO,.,). However, in all cases the coefficient of the Warburg impedance is much higher than the theoretical value. This fact is interpreted in terms of the surface oxid
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