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Study of the fluorite–pyrochlore–fluorite phase transitions in Ln2Ti2O7(Ln=Lu, Yb, Tm)

✍ Scribed by A. V. Shlyakhtina; L. G. Shcherbakova; A. V. Knotko; A. V. Steblevskii

Publisher
Springer
Year
2004
Tongue
English
Weight
344 KB
Volume
8
Category
Article
ISSN
1432-8488

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✍ Veronique Jubera; Pierre Gravereau; Jean-Pierre Chaminade; Claude Fouassier 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 380 KB

A new type of lithium rare earth oxyborate of formula Li 2 Ln 5 O 4 (BO 3 ) 3 (Ln ‫؍‬ Yb, Lu) has been discovered in the ternary phase diagrams Li 2 O+Ln 2 O 3 +B 2 O 3 . Single crystals of Li 2 Yb 5 O 4 (BO 3 ) 3 were grown by the 6ux method. The structure of this oxyborate was solved from a data c