Study of the Energetics and Dynamics of Hydrogen Bond Formation in Aliphatic Carboxylic Acid Vapors by Resonant Photoacoustic Spectroscopy
✍ Scribed by Winkler, A.; Hess, P.
- Book ID
- 127305432
- Publisher
- American Chemical Society
- Year
- 1994
- Tongue
- English
- Weight
- 954 KB
- Volume
- 116
- Category
- Article
- ISSN
- 0002-7863
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Proton (deuteron) transfer ofhydrogen bonds in benzoic, glutark and pformylbenzoic acids was studied by proton (deuteron) T, measurements. Deuteration of carboxylic protons was found to increase the barriers to classical proton jumping as well as quantum-mechanical tunneling. The former barriers inc
## Abstract During UV.‐irradiation of aliphatic carboxylic acids and esters in aqueous and nonaqueous solutions various alkyl and acyl type radicals derived from parent compounds and solvents have been observed by ESR.‐spectroscopy. The structures of the radicals point to α‐cleavage, β‐dehalogenati