Study of the coordination of Cu2+ in zeolite Y: Interaction with water and ammonia
β Scribed by Annelies Delabie; Kristine Pierloot; Marijke H Groothaert; Bert M Weckhuysen; Robert A Schoonheydt
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 253 KB
- Volume
- 37
- Category
- Article
- ISSN
- 1387-1811
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π SIMILAR VOLUMES
The ESR technique has been used to study the localization of copper@) ions in the zeoijte framework. In the enti@y hydrated samples the copper(H) ion is in the form of an hexazquo complex localized in the centre of the supercage. Dehydration produces the migration qf the ion toward the sodalite cage
Cu C ions in zeolites activate organic molecules containing p electrons by p back donation, which results in a distinct weakening of multiple bonds. In this study, we followed the activation of alkenes (ethene and propene) by Cu C ions in CuY and CuX zeolites of various Cu content. We also studied t
Molecular motions in the liquid phase in the faujasitc cavities of a fully hydrated Y zeolite have been studied by the electron spin relaxation of the copper ion.