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Study of the compositional heterogeneity of ethylene/1–hexene copolymers produced over supported catalysts of different composition

✍ Scribed by Mikhail A. Matsko; Ludmila G. Echevskaya; Marina P. Vanina; Marina I. Nikolaeva; Tatyana B. Mikenas; Vladimir A. Zakharov

Book ID: 112001960
Publisher: John Wiley and Sons
Year: 2012
Tongue: English
Weight: 437 KB
Volume: 126
Category: Article
ISSN: 0021-8995
DOI: 10.1002/app.36643

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Full Paper: Copolymerization of ethylene and 1-hexene was carried out with different catalysts: homogeneous Et[Ind] 2 ZrCl 2 , Cp 2 HfCl 2 and [(C 5 Me 4 )SiMe 2 N(tert-Bu)]TiCl 2 , the corresponding in-situ supported metallocenes, and combined in-situ supported metallocene catalysts (mixtures of Et