The automatic registration of potentiostaticcurrent/time diagrams was carried out, together with radiometric control of the true metal dissolution rate. The sensitivity attained permits fairly accurate measurement of the real dissolution rate of the passive tracer iron anode, not only in the station
Study of the chemical passivation of iron by phosphonates
✍ Scribed by Dipl.-Chem. A. Veres; Prof. Dr. G. Reinhard; Dr. E. Kálmán
- Publisher
- John Wiley and Sons
- Year
- 1992
- Tongue
- German
- Weight
- 466 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0947-5117
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✦ Synopsis
Abstract
The effect of some phosphonic acids (HMEP, NTMP, HEDP) on the chemical passivation of iron by dissolved oxygen in neutral aqueous solutions has been investigated. It has been shown that in the presence of phosphonic acids chemical passivation cannot be attained. This effect is due to the formation of soluble complexes as could be shown by the stability constants determined.
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