Study of the catalytic dehydrochlorination of 1,2-dichloropropane
β Scribed by Dzh. Yu. Nadzhafov
- Book ID
- 111463748
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2011
- Tongue
- English
- Weight
- 233 KB
- Volume
- 84
- Category
- Article
- ISSN
- 1070-4272
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The thermal decomposition of 1,2-dichloropropane at atmospheric pressure has been studied in the temperature range 227-59OoC, in a flow system. Above 45OoC, the reaction is homogenous and unimolecular with a rate constant: Below 45OoC, a low activation energy, probably heterogenous process competes
The influence of pre-reactor and reactor temperatures on the conversion of 1,3-dichloropropan-2-ol and the selectivity of its transformation to epichlorohydrin in continuous dehydrochlorination for two modes of the reaction product collection was studied. The dehydrochlorination process and mechanis