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Study of the anion-induced adsorption of In(III) from iodide solutions at the dme by ac measurements

✍ Scribed by M.C. Montemayor; E. Fatas


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
500 KB
Volume
33
Category
Article
ISSN
0013-4686

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✦ Synopsis


The reduction of In(llI) in solutions containing 0.5, 0.75 and 1 M of NaI and with an ionic strength of 1.00 maintained with sodium perchlorate, has been studied by measuring the interfacial admittance spectra at different dc potentials of the dropping mercury electrode (dme). The frequency dependence of the admittance corresponds to that of a reversible electrode reaction with reactant adsorption. The adsorption parameters have been determined and the strange behaviour of u', which increases with cathodic potential must be pointed out. This Seems to indicate that the adsorption occurs beyond the potential at which begin the reduction of indium. It is shown that the potential dependence of the adsorption parameters can he mathematically described by a Langmuir isotherm with the adsorption free energy being at least a quadratic function of potential. Strong adsorption effects have not been found.


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