𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Study of the Alkaline Hydrolysis of the Azetidin-2-one Ring by ab initio Methods: Influence of the solvent

✍ Scribed by Juan Frau; Josefa Donoso; Francisco Muñoz; Bartolomé Vilanova; Francisco García-Blanco

Publisher
John Wiley and Sons
Year
1997
Tongue
German
Weight
478 KB
Volume
80
Category
Article
ISSN
0018-019X

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Study of the conformers of dichloromethy
Study of the conformers of dichloromethylmethyldifluorosilane by vibrational spectroscopy and ab initio methods
✍ Valdemaras Aleksa; Peter Klaeboe; Anne Horn; Claus. J. Nielsen; Gamil A. Guirgis 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 421 KB 👁 2 views

## DichloromethylmethyldiÑuorosilane was synthesized for the Ðrst time. Raman spectra of the (CHCl 2 SiF 2 CH 3 ) liquid were obtained at various temperatures between 298 and 163 K. Spectra of the amorphous solid were recorded at 85 K and spectra of crystalline solids cooled by di †erent technique

Ab initio study of the oxidation of NCN
Ab initio study of the oxidation of NCN by O2
✍ R. S. Zhu; M. C. Lin 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 118 KB

## Abstract The reaction of NCN with O~2~ has been investigated by ab initio molecular orbital and transition state theory calculations. The mechanisms for formation of possible product channels involved in the singlet and triplet potential energy surfaces have been predicted at the highest level o

Solvent effect on the alkaline hydrolysi
Solvent effect on the alkaline hydrolysis of 2-thiophenyl- 3,5-dinitropyridine
✍ Magda F. Fathalla 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 117 KB

## Abstract The kinetics of the alkaline hydrolysis of 2‐thiophenyl‐3,5‐dinitropyridine were studied spectrophotometrically in different aquo‐organic solvents such as methanol, ethanol, __n__‐propyl alcohol, __iso__‐propyl alcohol, __t__‐butyl alcohol, acetonitrile, dimethyl sulfoxide, dioxane, and

Comparative study of the cationic surfac
Comparative study of the cationic surfactants and their influence on the alkaline hydrolysis of acetylsalicylic acid
✍ Birendra Kumar; Kallol K. Ghosh; P. Rodriquez Dafonte 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 248 KB

## Abstract A kinetic study of the reaction of acetylsalicylic acid (aspirin) with sodium hydroxide has been studied in the presence of some conventional and novel cationic surfactants. The pseudo‐first‐order rate constant increases with the surfactant concentration initially and then decreases. In

Ab initio MO study of the solvent effect
Ab initio MO study of the solvent effect on the SN2 reaction of the trimethylsulfonium cation with chloride anion
✍ Osamu Kikuchi; Yoko Sano; Ohgi Takahashi; Kenji Morihashi 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 524 KB

A recently developed ab initio MO theory including solvent effects has been applied to a typical cation-anion reaction, the SN2 reaction of the trimethylsulfonium cation with the chloride anion. In the gas phase, the trimethylsulfonium and chloride ions are unstabilized, and the reaction is expected