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Study of substrate dependence on the chemoselectivity of the gold-catalysed cycloisomerisation of aryl substituted 1,7-enynes

✍ Scribed by Huang, Chuhui; Kothandaraman, Prasath; Koh, Bing Qin; Chan, Philip Wai Hong


Book ID
118150626
Publisher
Royal Society of Chemistry
Year
2012
Tongue
English
Weight
383 KB
Volume
10
Category
Article
ISSN
1477-0520

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Primary dependence of 7-aryl-2,5-di-t-bu
✍ Ken'ichi Takeuchi; Hiroshi Fujimoto; Kunio Okamoto πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 245 KB

l3 C NMR studies showed that the population of the norcaradiene form of the title systems containing p-CH30, H, and p-CF3 on the 7-aryl group increases in this order. The result is consistent with the prediction from the n-acceptor strength of the aryl group estimated by INDO calculations.