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Study of structural change in linear polyethylene by elongation in view of behaviour of free radicals induced by γ-irradiation

✍ Scribed by N Kusumoto; Y Haga; Y Motozato

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
331 KB
Volume
16
Category
Article
ISSN
0032-3861

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Studies on Radical Cations I. Molecular
Studies on Radical Cations I. Molecular and electronic structure of [3]radialene cation produced by γ-irradiation in condensed phase
✍ Thomas Bally; Edwin Haselbach; Zuzana Lanyiova; Peter Baertschi 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 German ⚖ 780 KB

## Abstract γ‐Irradiation of tris (methylidene)‐cyclopropane (‘[3]radialene’) **1** in a rigid electron scavenging matrix (butylchoride/i‐pentane, 1:1) at 77 K leads to formation of its molecular cation **1**^+^. Slight softening of the matrix by a temperature increase of 3–5 K results in formation