The slow molecular motion of several de&rated and undeuterated spin probes differing in size and shape, embedded in a model glycerol-water matrix, have been studied by double-modulated electron spin resonance (DMESR). The DMESR spectra as a function of temperature reveal two motional regions. From t
Study of slow molecular motion of spin probes in polymers by the double-modulation ESR method
β Scribed by Valic, S.; Rakvin, B.; Veksli, Zorica; Grubisic-Gallot, Z.
- Book ID
- 127067984
- Publisher
- American Chemical Society
- Year
- 1990
- Tongue
- English
- Weight
- 632 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0024-9297
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π SIMILAR VOLUMES
The double-modulation ESR spin-probe technique was emmotion regime, the homogeneous linewidth (1/T 2 ) is larger ployed to study slow-motional dynamics in amorphous polymer than 1/T 1 , one can expect that the measurement of T 1 would matrices of polybutadiene, polyisobutylene, poly(methyl methacmak
## Abstract The rotational mobility of molecules in glassy polymers was investigated by quantitative simulations of electron spin resonance spectra of nitroxide spin probes with molecules of different sizes. The motional models were determined unambiguously when the experimental and calculated spec