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Study of slow molecular motion of spin probes in polymers by the double-modulation ESR method

✍ Scribed by Valic, S.; Rakvin, B.; Veksli, Zorica; Grubisic-Gallot, Z.


Book ID
127067984
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
632 KB
Volume
23
Category
Article
ISSN
0024-9297

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πŸ“œ SIMILAR VOLUMES


Slow molecular motion of different spin
✍ S. ValiΔ‡; B. Rakvin; Z. Veksli; S. Pečar πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 492 KB

The slow molecular motion of several de&rated and undeuterated spin probes differing in size and shape, embedded in a model glycerol-water matrix, have been studied by double-modulated electron spin resonance (DMESR). The DMESR spectra as a function of temperature reveal two motional regions. From t

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✍ B Rakvin; Z Veksli πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 English βš– 137 KB

The double-modulation ESR spin-probe technique was emmotion regime, the homogeneous linewidth (1/T 2 ) is larger ployed to study slow-motional dynamics in amorphous polymer than 1/T 1 , one can expect that the measurement of T 1 would matrices of polybutadiene, polyisobutylene, poly(methyl methacmak

Molecular mobility of nitroxide spin pro
✍ Daria A. Chernova; Andrey Kh. Vorobiev πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 480 KB πŸ‘ 1 views

## Abstract The rotational mobility of molecules in glassy polymers was investigated by quantitative simulations of electron spin resonance spectra of nitroxide spin probes with molecules of different sizes. The motional models were determined unambiguously when the experimental and calculated spec