Study of rotational isomerism in arylmethanesulfonates
β Scribed by B. A. Arbuzov; A. B. Remizov; G. G. Butenko; A. N. Vereshchagin
- Book ID
- 112440058
- Publisher
- Springer
- Year
- 1978
- Tongue
- English
- Weight
- 310 KB
- Volume
- 27
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
Molecular models suggest that "ergopinakol" (bisergostatrienol) (I) (2,3), the ~11 known irradiation product frcm ergo&en& should exist in twc isaaeric forms due to hindrance to rotation about the 7,7' bond. We now wish to report the resolution of the rotsmer mixture.
The vibrntional apcctrum of triethylaminc was investigated which reveals the presence of at least two rotational isomers. Those isomers arc prcsont in botb tho liquid and solid states. The TGG' configuration is tho more stable configuration in vapour phase.