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Study of reaction of poly(butyl acrylate) radical with cobalt-porphyrin

✍ Scribed by I. S. Morozova; A. G. Oganova; V. S. Nosova; D. D. Novikov; B. R. Smirnov


Book ID
112446960
Publisher
Springer
Year
1987
Tongue
English
Weight
237 KB
Volume
36
Category
Article
ISSN
1573-9171

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Reactions of radicals with polymersβ€”III.
✍ N.A. Weir; M. Rujimethabhas πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 English βš– 506 KB

The kinetics of H abstraction by methyl and tert.butyl radicals from poly(p-tert.butyl styrene) (PTL3) films (5 Γ— 10 3 mm thick) have been investigated at 298 K, both radicals being produced from the polymer by its exposure to short-wave u.v. radiation (2 = 254 nm) at pressures < 10 -4 Pa. Different