The intensity of scattering at 90 8 (I 90 8 ) of a solution of PS 12 PAA 12 copolymer (c P = 2.04 6 10 -3 g/cm 3 ) in 1,4-dioxane/H 2 O mixtures as a function of % H 2 O content W H 2 O .
Study of polystyrene-poly(tert-butyl acrylate) heteroarm star copolymers in dilute solutions
β Scribed by Constantinos Tsitsilianis; Ourania Kouli
- Publisher
- John Wiley and Sons
- Year
- 1995
- Tongue
- English
- Weight
- 331 KB
- Volume
- 16
- Category
- Article
- ISSN
- 1022-1336
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β¦ Synopsis
Abstract
Heteroarm star copolymers with polystyrene and poly(tertβbutyl acrylate) arms are studied in dilute solutions by means of viscometry and static light scattering. In a weakly selective solvent a segregatedβnonsegregated conformational transition is observed induced by temperature change. In a strongly selective solvent association phenomena take place and the heteroarm star molecules form multimolecular micelles.
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