Study of poly(St/BA/MAA) copolymer latexes with trimodal particle size distribution

✍ Scribed by Fuxiang Chu; Jean Guillot; Alain Guyot

• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: English
• Weight: 158 KB
• Volume: 9
• Category: Article
• ISSN: 1042-7147
• DOI: 10.1002/(sici)1099-1581(199812)9:12<844::aid-pat850>3.0.co;2-#

✦ Synopsis

A new strategy was developed for producing a polymer latex with trimodal particle size distribution by adding a second seed of polymer particles and some additional surfactants during polymerization. The polymerization was investigated by following the variation of the particle size, the size distribution, the number of particles, the surface tension and surfactant surface coverage at different stages of the polymerization process. The results showed that both the size and the size distribution can be easily controlled by varying the amount of additional surfactants and the second seed of polymer particles. The secondary nucleation was achieved when the surface coverage of particles was over 70%, and the amount of small particles formed increased with increasing amount of additional surfactants. The introduction of the additional surfactants had no significant effect on the size and number of middle particles, but reduced the size of large particles and caused the number of large particles to remain more stable because of the suppression of limited flocculation.