Study of Oxidation-Reduction Systems II. The reversible systems Ce+4Ce+3 AND Co+3Co+2
β Scribed by F. Verbeek; Z. Eeckhaut
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 901 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0037-9646
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π SIMILAR VOLUMES
Phase equilibria in the system Pr+Co+O at 1100 and 11503C are established by changing the oxygen partial pressure from 0 to 12.00 in Ψlog (P O 2 /atm), and a representative phase diagram at 11003C is presented for the Pr 2 O 3 +Co+CO 2 O 3 system. Under experimental conditions, the PrO 1.63Ψ ( ), Pr
It is confirmed that in divided cells, the oxidation of Ce(III) to Ce(IV) is possible with good current efficiency in many electrolytes. On the other hand, it is difficult to achieve such efficiency in undivided cells but it is possible using an emulsion of nitric acid/n-hexane containing tributylph