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Study of mechanism of Z, E-isomerization of α-nitro-β-arylaminoacrylic esters in solution employing dynamic NMR spectroscopy

✍ Scribed by V. I. Bakhmutov; V. A. Burmistrov; K. K. Babievskii; É. I. Fedin; V. M. Belikov

Book ID: 112447868
Publisher: Springer
Year: 1977
Tongue: English
Weight: 247 KB
Volume: 26
Category: Article
ISSN: 1573-9171
DOI: 10.1007/bf00958742

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## Abstract Fast __Z__, __E__‐isomerization of α‐nitro‐β‐indolylacrylates in polar solvents has been studied by dynamic ^1^H NMR spectroscopy. With indolylnitroacrylates having no substituents at the ring nitrogen atom, isomerization proceeds via intermediate formation of a mesomeric anion and ioni