๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Study of kinetics and mechanisms of some unimolecular reactions on silica surfaces

โœ Scribed by Brei, V. V.; Gun'ko, V. M.; Dudnik, V. V.; Chuiko, A. A.


Book ID
115504117
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
713 KB
Volume
8
Category
Article
ISSN
0743-7463

No coin nor oath required. For personal study only.


๐Ÿ“œ SIMILAR VOLUMES


Mechanism and Kinetics of Hexamethyldisi
โœ V.M. Gun'ko; M.S. Vedamuthu; G.L. Henderson; J.P. Blitz ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 243 KB

Quantum chemical calculations of the reaction of hexamethyldisilazane with silica indicates a two-step mechanism. The first, rate-determining step results in trimethylsilylation of a surface silanol and formation of trimethylaminosilane. The second step involves reaction of a trimethylaminosilane re